Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems
نویسندگان
چکیده
The ACl-ThCl4 (A = Li, Na, K) systems could be of relevance to the nuclear industry in near future. A thermodynamic investigation three binary is presented herein. excess Gibbs energy liquid solutions described using quasi-chemical formalism quadruplet approximation. phase diagram optimisations are based on experimental data available literature. stability increases order Li < Na K, agreement with idealised interactions and structural models.
منابع مشابه
Study OF binary SYSTEMS NdF3- MF (M = Li, Na, K): experimental, modeling and thermodynamic computation
The excess molar enthalpies HEm of the binary systems MF-NdF3 (M = Li, Na, K) were measured in the present work by high temperature calorimetry on a wide temperature (1220 K < T < 1400 K) and composition range. Some points of the equilibrium phase diagram have been also obtained by differential thermal analysis. Using the Hoch-Arpshofen model we represent the excess quantities of different syst...
متن کاملInternal Cation Mobilities in the Molten Binary Systems (Li, Na)Cl and (Na, K)C1
Internal mobility ratios of the two cations in the molten binary systems (Li, Na)Cl and (Na, K)C1 have been measured with Klemm's column method. From these and available data on the densities and conductivities the internal mobilities bLi, bNa and bK have been calculated. In (Li, Na)Cl, bLi is smaller than fcNa in the investigated composition and temperature range, and in (Na, K)C1, the Chemla ...
متن کاملThe Li+-Na+ exchange and Na+-K+-Cl- cotransport systems in essential hypertension.
This review examines the physiological functions of the Li+-Na+ exchanger and Na+-K+-Cl- cotransport system in human red blood cells. Both transporters are family aggregated and determined mainly by genetic factors; they are present in kidney and vascular cells, where they are regulated by vasoactive substances. To assess the physiological function of these two transporters, we investigated the...
متن کاملRed Blood Cell Li + - Na + Countertransport , Na + - K + Cotransport
Red blood cell Li-Na countertransport and Na-K cotransport activities, home blood pressure, invasive systemic hemodynamics, and limb venous compliance were measured in 65 white men (23 normotensive, 22 borderline hypertensive, and 20 mild essential hypertensive subjects). Li-Na countertransport activity was positively and significantly correlated with subject-determined home systolic blood pres...
متن کاملCytotoxicity effects of synthesized ZnO and Zn0.97X0.03O (X=Li, Na, and K) nanoparticles by the gelatin-based sol-gel method
Objective: In this study we would like to report the synthesis of pure and group I element doping of ZnO nanoparticles (ZnO-NPs) prepared using gelatin. The use of natural polymers for the preparation of the pure and doped nanoparticles can result in achieving low cost and eco-friendly advantages.Materials and Method: Pure and doped ZnO-NPs were obtained at 500 °C and The cytotoxicity of nanopa...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Thermo
سال: 2021
ISSN: ['2673-7264']
DOI: https://doi.org/10.3390/thermo1020009